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The main contribution of organic mat-  surface, a factor that influences the orig-
               chimneys with different hydrate satura-  in yellow below the BSR suggest the exis-
               tions. The inversion of the CSEM data re-  tence of a zone of higher concentration                                ter in the formation of GH was marine or-  inal organic matter and, therefore, masks
               veals that the largest resistivity anomalies   of free gas. The acoustic data (amplitude                          ganic carbon based on the results of the   the ages of the organic matter.
                                                                                                                                                            13
               within the gas hydrate stability zone are   anomalies below the BSR) encompass this                               stable isotope of carbon (δ C-org) and      Gas hydrate accumulations near the
               possibly associated with gas hydrate sat-  anomalous CSEM zone.                                                   total organic carbon/total nitrogen ratios   seafloor in RGC pockmarks appear to
               urations. Note that the CSEM anomalies                Source: Authors elaboration, 2022                           (RODRIGUES  et al., 2019). Rodrigues et.   be associated with pockets of gas from
                                                                                                                                 al, (2019) observed a contribution of fluids   shallow depths (tens of meters below
                 The gas in the hydrate is primarily meth-  origin of the gases was classified as bio-                           from deep sediments, which transported   the seafloor – Rodrigues  et al., 2017)
               ane with traces of ethane, and the stable   genic. Likewise, studies of free gases in                             “old” organic compounds (> 50 ka) to the   which, in turn, support chemosynthetic
               carbon isotopes of the  methane indicate   sediments were produced by microbial

                                 13
               a microbial origin (δ C values  from -69.3   methanogenesis, that is, gaseous hydrocar-                            Figure Z7
               to -66.7; Miller et al., 2015; Rodrigues et   bons were generated mainly through the
               al., 2019). According to the diagrams, the   microbial reduction of CO2 (Figure Z6).                               Images obtained
                                                                                                                                  in the area
                                                                                                                                  of   PC22 in
                                                                                                                                  which tubular
                            Figure Z6: Relationship between the values  of δ C H                                                  polychaetes

                                                                          13
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                             and δ CH  for samples from different areas of the                                                    of the genus
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                            Thernjlogenic C ;                                                                                     cruises.
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                      -80       -70        -60       -50        -40        -30       -20
                                                   o 13 C of CH  4
                                                                    Source: Authors elaboration, 2022                            Source: Medina-Silva
                                                                                                                                 (2018)
     638   BLUE ECONOMY                                                                                                                                                               State of the Art of Gas Hydrate Occurrences  639
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