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The main contribution of organic mat-  surface, a factor that influences the orig-
 chimneys with different hydrate satura-  in yellow below the BSR suggest the exis-
 tions. The inversion of the CSEM data re-  tence of a zone of higher concentration   ter in the formation of GH was marine or-  inal organic matter and, therefore, masks
 veals that the largest resistivity anomalies   of free gas. The acoustic data (amplitude   ganic carbon based on the results of the   the ages of the organic matter.
                                             13
 within the gas hydrate stability zone are   anomalies below the BSR) encompass this   stable isotope of carbon (δ C-org) and   Gas hydrate accumulations near the
 possibly associated with gas hydrate sat-  anomalous CSEM zone.  total organic carbon/total nitrogen ratios   seafloor in RGC pockmarks appear to
 urations. Note that the CSEM anomalies   Source: Authors elaboration, 2022  (RODRIGUES  et al., 2019). Rodrigues et.   be associated with pockets of gas from
                   al, (2019) observed a contribution of fluids   shallow depths (tens of meters below
 The gas in the hydrate is primarily meth-  origin of the gases was classified as bio-  from deep sediments, which transported   the seafloor – Rodrigues  et al., 2017)
 ane with traces of ethane, and the stable   genic. Likewise, studies of free gases in   “old” organic compounds (> 50 ka) to the   which, in turn, support chemosynthetic
 carbon isotopes of the  methane indicate   sediments were produced by microbial

 13
 a microbial origin (δ C values  from -69.3   methanogenesis, that is, gaseous hydrocar-  Figure Z7
 to -66.7; Miller et al., 2015; Rodrigues et   bons were generated mainly through the
 al., 2019). According to the diagrams, the   microbial reduction of CO2 (Figure Z6).  Images obtained
                   in the area
                   of   PC22 in
                   which tubular
 Figure Z6: Relationship between the values  of δ C H    polychaetes

 13
 6
 2
 and δ CH  for samples from different areas of the   of the genus
 13
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 Rio Grande Cone (CONEGAS Project, 2021)  Escarpia
                   occur, the
                   most frequent
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 N   -50  -------------  --�:------------�---r------ 1 ----------r-----------------r-----------------T-----------------  •ROV  operated vehicle
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 -40  -----------------�-----------------r------ 1 ----------�-----------------r-----------------T-----------------·   •PC92  underwater
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 Thermogenic CH anjd C 2  both used in
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 -30  -----------------  -----------------·-------�---------�-----------------�----------------- 1-----------------  the CONEGAS
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 Microbjial CH an�   project scientific
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 Thernjlogenic C ;  cruises.
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 -80  -70  -60  -50  -40  -30  -20
 o 13 C of CH  4
 Source: Authors elaboration, 2022  Source: Medina-Silva
                   (2018)
 638   BLUE ECONOMY                                                    State of the Art of Gas Hydrate Occurrences  639
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